Formal aromaticity transfer for palladium-catalyzed coupling between phenols and pyrrolidines/indolines† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02578e Click here for additional data file.
نویسندگان
چکیده
We herein describe a palladium-catalyzed formal aromaticity transfer coupling reaction between phenols and pyrrolidines or indolines to generate the corresponding N-cyclohexyl pyrroles or indoles. In this transformation, the aromaticity of phenols is formally passed on to the pyrrolidine or indoline units. Substituted phenols thus can serve as latent cyclohexyl equivalents for the fast construction of various N-cyclohexyl pyrroles and indoles.
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State Key Laboratory of Organometallic Bio-Organic and Natural Products Chem Chemistry, Chinese Academy of Sciences, China. E-mail: [email protected]; kdin Department of Chemistry, South Universi Shenzhen 518055, China. E-mail: oscarchun University of Chinese Academy of Sciences, Collaborative Innovation Center of Chem 300071, China † Electronic supplementary information 1517578. For ESI an...
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